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Retraction of “Bisboronic Acids for Selective, Physiologically Relevant Direct Glucose Sensing with Surface-Enhanced Raman Spectroscopy”
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2024-11-18 , DOI: 10.1021/jacs.4c11001
Bhavya Sharma, Pradeep Bugga, Lindsey R. Madison, Anne-Isabelle Henry, Martin G. Blaber, Nathan G. Greeneltch, Naihao Chiang, Milan Mrksich, George C. Schatz, Richard P. Van Duyne

The first author requests retraction of the paper titled “Bisboronic Acids for Selective, Physiologically Relevant Direct Glucose Sensing with Surface-Enhanced Raman Spectroscopy”. In this paper, the Raman shift axes for all spectra were calibrated, as is standard in the field, using cyclohexane as a calibration standard; however, the bisboronic acid (BBA) spectrum shown in Figure 3 and used in the difference spectra suffered an unknown error, which was recalibrated by shifting the spectra to correspond to established BBA peak positions. The spectrum was then subtracted from the glucose plus BBA spectra. The shift in the BBA spectrum was not reported in the paper, and this results in the difference spectra shown in Figures 3 and 4 being falsified. Additionally, the difference spectra shown in Figures 3 and 4 are inconsistent with the difference spectra used to generate the data presented in Figure 5. As a result, the first author is not confident that the conclusions in the paper regarding glucose detection are sound or reproducible. The coauthors support the decision to retract. The original Article was published on September 26, 2016, and retracted on November 18, 2024. This article has not yet been cited by other publications.

中文翻译:


“使用表面增强拉曼光谱进行选择性、生理相关的直接葡萄糖传感的双硼酸”的撤回



第一作者要求撤回题为“Bisboronic Acids for Selective, Physiologically Related Direct Glucose Sensing with Surface-Enhanced Raman Spectroscopy”的论文。在本文中,使用环己烷作为校准标准,按照现场标准校准了所有光谱的拉曼位移轴;但是,图 3 所示并用于差异谱图的双硼酸 (BBA) 谱图出现了未知误差,通过移动谱图以对应于已建立的 BBA 峰位置来重新校准该误差。然后从葡萄糖加 BBA 光谱中减去光谱。论文中没有报道 BBA 谱图的偏移,这导致图 3 和图 4 所示的差异谱图被证伪。此外,图 3 和图 4 所示的差异谱图与用于生成图 5 中所示数据的差异谱图不一致。因此,第一作者对论文中关于葡萄糖检测的结论是否合理或可重复没有信心。合著者支持撤回的决定。原始文章发表于 2016 年 9 月 26 日,并于 2024 年 11 月 18 日撤回。本文尚未被其他出版物引用。
更新日期:2024-11-18
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