Inspired by the perchlorate activation process in microbes, a dinuclear Fe-NHC (NHC=N-heterocyclic carbene) complex was developed in this work to facilitate the two-phase activation of perchlorate through the cooperation of bimetallic centers. With the aid of photoirradiation, the oxidative potential of perchlorate could be released in a controllable manner to achieve the homocoupling of hydrocarbon substrates.

中文翻译：

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通过二核 Fe-NHC（N-杂环卡宾）络合物实现两相高氯酸盐活化


受微生物中高氯酸盐活化过程的启发，本研究开发了一种双核 Fe-NHC （NHC=N-杂环卡宾） 复合物，通过双金属中心的合作促进高氯酸盐的两相活化。在光照射的帮助下，高氯酸盐的氧化电位可以以可控的方式释放，从而实现烃类底物的均偶联。