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The effect of Ce3+ ions on the optical, and radiation shielding properties in Ba–Sn borophosphate glass
Radiation Physics and Chemistry ( IF 2.8 ) Pub Date : 2024-10-30 , DOI: 10.1016/j.radphyschem.2024.112357
A. Paul Dhinakaran, P. Vinothkumar, S. Praveenkumar, Manoj Mohapatra

This study aims to investigate the structural, optical, and mechanical properties of Ce3+ doped Barium Tin Borophosphate glass for potential applications in nuclear radiation shielding. The Ce3+ Doped Barium Tin Borophosphate glass (50B2O3+20 P2O5+10TiO2+6SrCO3+4SnO+ 4BaF2+5BaCO3+1Ce2O3) was produced according to earlier research, melt quenching method. The amorphous nature of Ce3+ Doped Barium Tin Borophosphate glass was verified by powder X-ray diffraction investigation. The Ce3+ Doped Barium Tin Borophosphate glass's functional groups were determined using Fourier transform-RAMAN and Fourier transform infrared spectroscopy. Using Ultraviolet-Visible spectroscopy the Ce3+ Doped Barium Tin Borophosphate glass was examined. These properties included its optical band gap, extinction coefficient, optical conductivity, and refractive index. Using EDAX and SEM analyses, the chemical compositions and surface morphology of the Ce3+ Doped Barium Tin Borophosphate glass were examined. Ce3+ doped barium tin Borophosphate glass was studied in terms of its excitation and emission spectra using the photoluminescence technique. The glass's CIE coordinates were also looked at. Additionally, the mass attenuation coefficient, half-value layer, mean free path, tenth value layer, and EABF were studied concerning the glass's gamma-ray shielding qualities using the Phy-X software.

中文翻译:


Ce3+ 离子对 Ba-Sn 硼磷酸酯玻璃的光学和辐射屏蔽性能的影响



本研究旨在研究 Ce3+ 掺杂硼磷酸钡锡玻璃的结构、光学和机械性能,以用于核辐射屏蔽的潜在应用。Ce3+ 掺杂硼磷酸钡锡玻璃 (50B2O3+20 P2O5+10TiO2+6SrCO3+4SnO+ 4BaF2+5BaCO3+1Ce2O3) 是根据早期研究,熔融淬火法生产的。通过粉末 X 射线衍射研究验证了 Ce3+ 掺杂钡锡硼磷酸盐玻璃的非晶性质。采用傅里叶变换-拉曼和傅里叶变换红外光谱测定 Ce3+ 掺杂硼锡硼磷酸酯玻璃的官能团。使用紫外-可见光谱法检查了 Ce3+ 掺杂的硼磷酸钡锡玻璃。这些特性包括其光学带隙、消光系数、光导率和折射率。使用 EDAX 和 SEM 分析,检查了 Ce3+ 掺杂硼磷酸钡锡玻璃的化学成分和表面形貌。使用光致发光技术研究了 Ce3+ 掺杂钡锡硼磷酸盐玻璃的激发和发射光谱。还查看了玻璃的 CIE 坐标。此外,使用 Phy-X 软件研究了玻璃伽马射线屏蔽质量的质量衰减系数、半值层、平均自由程、第十值层和 EABF。
更新日期:2024-10-30
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