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Flash synthesis of high-performance and color-tunable copper(I)-based cluster scintillators for efficient dynamic X-ray imaging
npj Flexible Electronics ( IF 12.3 ) Pub Date : 2024-11-16 , DOI: 10.1038/s41528-024-00365-5
Wenjing Zhao, Yanze Wang, Ruizi Li, Xiaowang Liu, Wei Huang

Efficient scintillators are crucial for advancing X-ray imaging, requiring superior performance, customizable color, and cost-effectiveness. Despite progress in scintillator development, traditional synthesis methods suffer from extended reaction times, high processing temperatures, and labor-intensive post-treatment procedures. Herein, we introduce a rapid flash synthesis approach for high-performance Cu(I)-based cluster scintillators, achieved ordered assembly through solvent evaporation in 2 min. This innovative method not only accelerates synthesis but also yields scintillators with desirable features, such as wide-range luminescence tuning, a high photoluminescence quantum yield, and robust resistance to X-ray irradiation. The resulting flexible films from Cu(I)-based cluster scintillators demonstrate a low detection limit of 44 nGy s−1 and stable X-ray imaging capabilities with a resolution of 24.8 lp/mm. Additionally, the short luminescence lifetime allows the use of the flexible scintillation film for dynamic real-time imaging at a speed of 30 frames per second. The outcomes of this flash synthesis offer a strategic blueprint for the practical exploration of high-performance, large-scale, and swift synthesis of Cu(I)-based hybrid materials. This innovative technique holds the promise of significantly enhancing the efficiency and accessibility of advanced scintillators, making them more widely applicable in the field of X-ray imaging.



中文翻译:


高性能和颜色可调的铜 (I) 簇闪烁合成器,用于高效的动态 X 射线成像



高效的闪烁体对于推进 X 射线成像至关重要,需要卓越的性能、可定制的颜色和成本效益。尽管闪烁体开发取得了进展,但传统的合成方法存在反应时间长、加工温度高和劳动密集型后处理程序的问题。在此,我们介绍了一种用于高性能 Cu(I) 基簇闪烁体的快速闪光合成方法,该方法通过在 2 分钟内通过溶剂蒸发实现有序组装。这种创新方法不仅加速了合成,还产生了具有理想特性的闪烁体,例如宽范围发光调谐、高光致发光量子产率和强大的抗 X 射线照射能力。基于 Cu(I) 的簇闪烁体得到的柔性薄膜显示出 44 nGy s-1 的低检测限和稳定的 X 射线成像能力,分辨率为 24.8 lp/mm。此外,较短的发光寿命允许使用柔性闪烁膜以每秒 30 帧的速度进行动态实时成像。这种快速合成的结果为高性能、大规模和快速合成基于 Cu(I) 的混合材料的实际探索提供了战略蓝图。这项创新技术有望显著提高先进闪烁体的效率和可及性,使其在 X 射线成像领域得到更广泛的应用。

更新日期:2024-11-17
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