A nickel-catalyzed coupling between S-2-pyridyl thioesters and redox-active esters has been reported. Diludine was used as a reductant in this strategy. Our method rapidly achieves the target ketone products in moderate to good yield. The construction of nonanomeric C-acyl glycosides was realized through the approach as well.

中文翻译：

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使用有机还原剂通过 S-2-吡啶基硫酯和氧化还原活性酯之间的镍催化偶联获得酮


据报道，S-2-吡啶硫酯和氧化还原活性酯之间存在镍催化偶联。Diludine 在该策略中用作还原剂。我们的方法以中等到良好的收率快速获得目标酮产物。九异体 C-酰基糖苷的构建也是通过该方法实现的。