Carbon-based materials, such as activated carbon, graphene, graphitic carbon nitride, carbon nanotubes, carbon nanofibers, and other carbonaceous derivatives, are being considered as a promising strategy for catalyst immobilization because of their exceptional characteristics, such as large surface area, tailored surface functionalities, and high chemical stability. Their use as catalyst support in Suzuki coupling reactions has made a significant contribution to enhancing catalytic durability, reusability, and reaction selectivity. Although the Suzuki Miyaura coupling reaction is an industrial established process, but significant research in academia is currently being conducted to enhance the substrate scope, developing more efficient catalysts, and improve its practicality. This review provides a thorough analysis of the application of carbon-based materials as catalyst supports in Suzuki coupling reactions between the years 2015–2023. The synthesis methodologies used to produce carbon-based support and the processes involved in the immobilization of Suzuki coupling catalysts onto the supports have been discussed, providing insight into the influence of these materials on catalytic performance, reaction kinetics, and product yields. This review will provide insightful information to scientists and industry professionals to assist in directing future avenues for catalyst design and advance the development of more environmentally friendly and effective catalytic processes.

中文翻译：

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探索碳基材料作为 Suzuki-Miyaura 偶联反应的定制平台：综述


碳基材料，如活性炭、石墨烯、石墨氮化碳、碳纳米管、碳纳米纤维和其他碳质衍生物，因其特殊的特性（如大表面积、定制的表面官能团和高化学稳定性）而被认为是一种很有前途的催化剂固定化策略。它们在 Suzuki 偶联反应中用作催化剂载体，为提高催化耐久性、可重用性和反应选择性做出了重大贡献。虽然 Suzuki Miyaura 偶联反应是一个工业成熟的过程，但学术界目前正在进行重大研究，以扩大底物范围，开发更高效的催化剂，并提高其实用性。本文对 2015-2023 年期间碳基材料作为催化剂载体在 Suzuki 偶联反应中的应用进行了全面分析。讨论了用于生产碳基载体的合成方法以及将 Suzuki 偶联催化剂固定到载体上所涉及的过程，从而深入了解了这些材料对催化性能、反应动力学和产物收率的影响。本综述将为科学家和行业专业人士提供有见地的信息，以协助指导催化剂设计的未来途径，并推动更环保、更有效的催化工艺的开发。