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Azide-alkyne cycloaddition for polydimethysiloxane chemistry
Polymer Chemistry ( IF 4.1 ) Pub Date : 2024-11-15 , DOI: 10.1039/d4py01052c
Kseniya A. Bezlepkina, Sergey Milenin, Aziz Muzafarov

To be coPolydimethylsiloxanes (PDMS) occupy a special place among polymers due to their unique properties, including the possibility of their easy functionalization. Click chemistry reactions, in particular, the azide-alkyne cycloaddition reaction, are promising for the production of both functional siloxanes and siloxane copolymers, and for cross-linked materials. This review discusses the emergence and development of the azide-alkyne cycloaddition reaction for the synthesis of polydimethylsiloxane modification and structures based on them, as well as methods for introducing azide and acetylene fragments into the PDMS structure.nfirmed

中文翻译:


叠氮化物-炔烃环加成反应,用于聚二甲基硅氧烷化学



To be coPolydimethylsiloxanes (PDMS) 由于其独特的性能,包括易于官能化的可能性,在聚合物中占有特殊的地位。点击化学反应,特别是叠氮化物-炔烃环加成反应,有望用于生产官能硅氧烷和硅氧烷共聚物以及交联材料。本文讨论了用于合成聚二甲基硅氧烷改性的叠氮化物-炔烃环加成反应的出现和发展及其结构,以及将叠氮化物和乙炔片段引入 PDMS 结构的方法。
更新日期:2024-11-15
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