当前位置: X-MOL 学术Chem. Commun. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation
Chemical Communications ( IF 4.3 ) Pub Date : 2024-11-11 , DOI: 10.1039/d4cc05173d
Bing Zeng, Yuexin Wang, Kanghui Xiong, Keke Zhang, Siyu Zhang, Xianjun Lang

A zirconium metal–organic framework (MOF), NU-1003, along with TEMPO (2,2,6,6-tetramethylpiperidine-N-oxyl), is constructed as a system of cooperative photocatalysis for blue light-powered aerobic sulfoxidation. The incorporation of 4 mol% of TEMPO enhances the hole transfer and thereby aerobic sulfoxidation by NU-1003 photocatalysis, demonstrating the pivotal role of a redox mediator in transforming an established MOF.

中文翻译:


使用 TEMPO 进行金属锆-有机框架光催化进行蓝光有氧硫氧化



锆金属有机框架 (MOF) NU-1003 与 TEMPO (2,2,6,6-四甲基哌啶-N-氧基) 一起构建为用于蓝光驱动有氧硫氧化的协同光催化系统。4 mol% 的 TEMPO 的掺入增强了空穴转移,从而通过 NU-1003 光催化进行了有氧硫氧化,证明了氧化还原介质在转化已建立的 MOF 中的关键作用。
更新日期:2024-11-12
down
wechat
bug