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Electrocatalytic reduction of N2 to NH3 by MIL-88-derived pod-like Fe7Se8/C nanomaterials under ambient conditions
Chemical Communications ( IF 4.3 ) Pub Date : 2024-11-11 , DOI: 10.1039/d4cc04683h
Gongyao Nie, Huanhuan Zhang, Lanhua Yi, Xiao Ma, Wei Yi, Jiawei Wan, Yebo Lu, Xingzhu Wang

In this paper, pod-like Fe7Se8/C nanocomposite catalyst materials were prepared by MIL-88 selenide annealing and the as-prepared Fe7Se8/C nanocatalyst exhibited excellent electrocatalytic performance in neutral electrolyte for the electrocatalytic nitrogen reduction reaction (eNRR). The average ammonia yield rate was 7.11 μg h−1 mgcat−1 with a corresponding faradaic efficiency (FE) of 10.44% obtained at the optimum potential of −0.3 V. Moreover, the as-prepared Fe7Se8/C electrocatalyst shows good selectivity and stability for the eNRR.

中文翻译:


MIL-88衍生的pod状Fe7Se8/C纳米材料在环境条件下电催化还原N2为NH3



本文通过MIL-88硒化物退火制备了pod状Fe7Se8/C纳米复合催化剂材料,所制备的Fe7Se8/C纳米催化剂在中性电解质中表现出优异的电催化性能,用于电催化氮还原反应(eNRR)。平均氨产率为 7.11 μg h-1 mg cat-1,在 -0.3 V 的最佳电位下获得相应的法拉第效率 (FE) 为 10.44%。此外,所制备的 Fe7Se8/C 电催化剂对 eNRR 表现出良好的选择性和稳定性。
更新日期:2024-11-11
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