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Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2016-11-07 07:11:29 , DOI: 10.1002/anie.201610384
Michael C. Thompson ₁ , Jacob Ramsay ₁ , J. Mathias Weber ₁

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Bismuth is vaporized by a pulsed UV laser (background) to create a plasma containing Bi⁻ anions, which are entrained into a supersonic expansion of CO₂, producing [Bi(CO₂)_n]⁻ clusters. In their Communication (DOI: 10.1002/anie.201607445), J. M. Weber et al. show that small clusters have core ions based on BiCOO⁻ metalloformate complexes (center). Solvation by an increasing number of CO₂ molecules leads to a change in the core ion structure from metalloformate to oxalate (foreground). Cover picture: the Weber group and Steve Burrows, JILA.

中文翻译：

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铋通过脉冲UV激光（背景）蒸发以产生含有Bi的等离子体^-阴离子，其被夹带到CO的超声膨胀₂，产生[铋（CO ₂）_Ñ ] ^-集群。JM Weber等人在其通讯（DOI：10.1002 / anie.201607445）中表明，小簇具有基于BiCOO芯离子^- metalloformate络合物（中心）。越来越多的CO ₂分子溶剂化导致核心离子结构从金属甲酸盐变为草酸盐（前景）。封面图片：Weber小组和JILA的Steve Burrows。

更新日期：2016-11-08

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