We have developed an efficient gold-catalyzed C–S cross-coupling of various silver-based thionucleophiles with aryl iodides. Our method offers a one-stop-shop solution for synthesizing diverse sulfur-containing aromatics, including aryl thiocyanic acids, aryl diethyldithiocarbamates, aryl sulfones, and aryl thiobenzoates. Our protocol gives moderate to excellent yields and compatibility with various functional groups. In comparison to other transition-metal-catalyzed C–S cross-couplings, our method has advantages in broad applicability and high tolerance toward air and moisture.

中文翻译：

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通过Au催化的C-S交叉偶联合成硫氰酸芳酯、芳基二硫代氨基甲酸酯、芳基砜和硫代苯甲酸芳酯


我们开发了一种高效的金催化 C-S 各种银基亲硫试剂与芳基碘化物的 C-S 交叉偶联。我们的方法为合成各种含硫芳烃提供了一站式解决方案，包括芳基硫氰酸、芳基二乙基二硫代氨基甲酸盐、芳基砜和芳基硫代苯甲酸盐。我们的方案可提供中等至极好的产量以及与各种官能团的兼容性。与其他过渡金属催化的 C-S 交叉偶联相比，我们的方法具有广泛的适用性和对空气和水分的高耐受性等优势。