Aqueous Zn metal batteries (AZMBs) offer a promising solution for grid‐scale energy storage. Nonetheless, their commercial deployment is hindered by pivotal challenges related to the Zn metal anode, particularly the morphological heterogeneity of electrodeposits and interfacial chemical instability arising from irreversible and uneven electrodeposition. Crystallographic texturing during Zn electrodeposition emerges as a robust approach to achieve grain‐refinement and chemically stable electrodeposits, thereby promoting the sustainable cycling of the Zn anode. Despite substantial progress in Zn texturing, a comprehensive review that systematically elucidates the principles and mechanisms underlying irregular morphological evolution and crystallographic texturing is still lacking. Therefore, this review addresses this gap by first examining the formation of these issues from a crystallographic perspective. The review then categorizes and details five distinct induction mechanisms for crystallographic texturing in Zn electrodeposits. Eventually, the review offers future perspectives on crystallographic texturing, aiming to advance the transition from academic research to industrial application of AZMBs.

中文翻译：

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用于可持续 Zn 阳极的电沉积的晶体学纹理


水系锌金属电池 （AZMB） 为电网规模的储能提供了一种很有前途的解决方案。尽管如此，与锌金属负极相关的关键挑战阻碍了它们的商业部署，特别是电沉积的形态异质性和不可逆和不均匀电沉积引起的界面化学不稳定性。Zn 电沉积过程中的晶体纹理成为实现晶粒细化和化学稳定电沉积的可靠方法，从而促进 Zn 阳极的可持续循环。尽管 Zn 纹理化取得了重大进展，但仍然缺乏系统阐明不规则形态演变和晶体纹理化的原则和机制的全面综述。因此，本综述首先从晶体学的角度研究这些问题的形成，从而解决了这一差距。然后，该综述对 Zn 电沉积中晶体纹理的五种不同的诱导机制进行了分类和详细说明。最终，该综述为晶体纹理化提供了未来前景，旨在推进 AZMBs 从学术研究向工业应用的过渡。