The interactions and contradictions among energy, resources, environment, human health and social development are perennial subjects of scientific research. Multifunctional, adjustable, and high-performance composite catalysts are an effective means of coordinating and resolving the tensions between social development, energy and the environment. Polyoxometalate chemistry, represented by polyoxometalates (POMs), has made a breakthrough due to its superior catalytic activity and wide range of applications. This has significantly promoted the combination of catalytic chemistry and production practice. Metal-organic frameworks (MOFs) are a class of porous materials that combine organic and inorganic properties. MOFs are highly crystalline and have a flexible structure with a large surface area. Combining POMs with MOFs to form POMOF-based materials offers the advantages of both materials and a synergistic effect greater than the sum of its parts. Although there have been several reviews on POMOF composites, especially in the field of catalysis, comprehensive discussions on the latest advances and specific applications remain limited. To promote the development of the field and explore the conformational relationship in depth, this review focuses on the frontiers of catalysis of POMOF-based materials. It discusses the composition, coupling strategy, and reaction mechanism of these materials using pioneering classifications and descriptions. A comprehensive review of research work in the field, classified by application areas, is presented to stimulate catalysis research and provide a new framework, new perspectives, and new horizons.

中文翻译：

---

基于 POMOF 的多功能材料：合成、机理、拓扑和催化应用


能源、资源、环境、人类健康和社会发展之间的相互作用和矛盾是科学研究的永恒主题。多功能、可调、高性能的复合催化剂是协调和解决社会发展、能源和环境之间紧张关系的有效手段。以多金属氧酸盐 （POM） 为代表的多金属氧酸盐化学因其卓越的催化活性和广泛的应用而取得了突破。这极大地促进了催化化学和生产实践的结合。金属有机框架 （MOF） 是一类结合了有机和无机特性的多孔材料。MOF 具有高结晶性，具有具有大表面积的柔性结构。将 POM 与 MOF 结合形成基于 POMOF 的材料具有两种材料的优点，并且协同效应大于其各部分的总和。尽管已经对 POMOF 复合材料进行了多次综述，尤其是在催化领域，但对最新进展和具体应用的全面讨论仍然有限。为推动该领域的发展，深入探讨构象关系，本文重点综述了POMOF基材料催化的前沿领域。它使用开创性的分类和描述讨论了这些材料的组成、偶联策略和反应机制。对该领域的研究工作进行了全面回顾，按应用领域分类，以促进催化研究并提供新框架、新视角和新视野。