Innovation in materials, aided by recent advancements in science and technology, is shaping a better future. Among these, porous materials, including covalent-organic frameworks (COFs), metal-organic frameworks (MOFs), organic polymers, zeolites, silica, and metal-polymer-coordination complexes (MPCCs), have garnered significant attention due to their rigid structure and higher stability with respect to humid conditions. MPCCs have been of particular interest lately. This review first compares MPCCs to MOFs and COFs, then focuses on their synthesis and properties. It also highlights the unique characteristics that distinguish MPCCs from MOFs and organic polymers. Subsequently, it discusses the use of MPCCs in generating polymeric gels and other applications such as catalysis, sensing, and adsorption/separation of organic molecules and gases. Finally, it delves into the challenges and prospects for their design, synthesis, characterization, properties, and applications. This review aims to guide researchers in exploring the potential of porous materials in various fields.

中文翻译：

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金属-聚合物配位复合物：一类权宜之计的杂化功能材料


在最新科学和技术进步的帮助下，材料创新正在塑造更美好的未来。其中，多孔材料，包括共价有机框架 （COF）、金属有机框架 （MOF）、有机聚合物、沸石、二氧化硅和金属聚合物配位络合物 （MPCC），由于其刚性结构和在潮湿条件下的较高稳定性而受到广泛关注。MPCC 最近特别受到关注。本文首先将 MPCC 与 MOF 和 COF 进行了比较，然后重点介绍了它们的合成和性质。它还强调了 MPCC 与 MOF 和有机聚合物区分开来的独特特性。随后，它讨论了 MPCC 在生成聚合物凝胶和其他应用中的应用，例如有机分子和气体的催化、传感和吸附/分离。最后，它深入探讨了其设计、合成、表征、特性和应用的挑战和前景。本文旨在指导研究人员探索多孔材料在各个领域的潜力。