Biosynthetic Origin of the Methoxy Group in Quinine and Related Alkaloids,Angewandte Chemie International Edition

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Biosynthetic Origin of the Methoxy Group in Quinine and Related Alkaloids
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-11-07 , DOI: 10.1002/anie.202418306
Blaise Kimbadi Lombe ₁ , Tingan Zhou ₁ , Lorenzo Caputi ₁ , Kerstin Ploss ₁ , Sarah E O'Connor ₁

Affiliation

Two substrates, tryptamine and 5-methoxytryptamine, are used in parallel by Cinchona to generate the naturally occurring mixtures of methoxy and non-methoxy Cinchona alkaloids. Discovery of the genes responsible for methoxylation allows reconstitution of biosynthetic intermediates in tobacco.

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