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Design, Synthesis, and Characterization of 1,3,5-Tri(1H-benzo[d]imidazol-2-yl)benzene-Based Fluorescent Supramolecular Columnar Liquid Crystals with a Broad Mesomorphic Range
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2014-08-21 00:00:00 , DOI: 10.1021/jo5016954
Jin-Feng Xiong 1 , Shi-He Luo 2 , Jing-Pei Huo 3 , Jin-Yan Liu 1 , Shui-Xia Chen 2 , Zhao-Yang Wang 1
Affiliation  

A new kind of supramolecular columnar liquid crystal T–A with a broad mesomorphic range (up to 164.9 °C), good thermal stability, and strong fluorescence is designed and formed by the H-bonding between 1,3,5-tri(1H-benzo[d]imidazol-2-yl)benzene (T) and serial gallic acid derivatives (A). Two components are easily available because of simple routes, common reactions, high yields, commercial starting materials, and inexpensive catalysts. The introduction of the 1,2,3-triazole structure into component A makes the textures different and is slightly disadvantageous for the T–A complexes.

中文翻译:

1,3,5-三(1 H-苯并[ d ]咪唑-2-基)苯型宽介晶范围的荧光超分子柱状液晶的设计,合成与表征

一种新的超分子柱状液晶的T-阿具有宽介晶范围(高达164.9℃),热稳定性好,与强荧光的设计和由1,3,5-三之间的1 H-接合(形成H-苯并[ d ]咪唑-2-基)苯(T)和没食子酸系列衍生物(A)。由于路线简单,通常的反应,高收率,商业原料和廉价的催化剂,很容易获得两种组分。在组分A中引入1,2,3-三唑结构会使质地不同,并且对T–A配合物不利。
更新日期:2014-08-21
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