ortho-Nitrosocumene (o-NC) exhibits dynamic N,N bonding, interchanging monomer and E/Z-azodioxide dimer structures, the extent of which depends on the environment. As a solid, o-NC is a Z-dimer; in organic solvent, the monomer is favored; and in water, dimers are favored. A supramolecular assembly of o-NC is observed as a separate species by NMR in water, shown to be a novel nanometer-sized aggregate containing ∼2000 molecules.

中文翻译：

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邻亚硝基异丙苯在有机溶剂和水中动态共价和非共价组装


邻位亚硝基异丙苯 （o-NC） 表现出动态 N，N 键合、交换单体和 E/Z-偶氮二聚体结构，其程度取决于环境。作为固体，o-NC 是 Z-二聚体;在有机溶剂中，单体受到青睐;在水中，二聚体受到青睐。通过核磁共振在水中观察到 o-NC 的超分子组装体作为单独的物质，显示是一种包含 ∼2000 个分子的新型纳米级聚集体。