A new microporous supramolecular-framework Ru(II)–porphyrin catalyst containing non-covalent interactions between pyrenylphenyl moieties at the meso-position of the porphyrin ring is synthesised and structurally characterised. This recyclable catalyst expedites styrene epoxidation more efficiently than homogeneous Ru–porphyrin catalytic systems.

中文翻译：

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用于苯乙烯环氧化的 Ru-卟啉基超分子框架催化剂的开发


合成了一种新的微孔超分子框架 Ru（II）-卟啉催化剂，该催化剂在卟啉环的介位处包含芘基苯基部分之间的非共价相互作用并进行了结构表征。这种可回收催化剂比均相 Ru-卟啉催化系统更有效地加速苯乙烯环氧化。