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Additions and Corrections to Cleavage of Si–H, B–H and C–H Bonds by Metal–Ligand Cooperation
Chemical Reviews ( IF 51.4 ) Pub Date : 2024-10-31 , DOI: 10.1021/acs.chemrev.4c00563
Takuya Higashi, Shuhei Kusumoto, Kyoko Nozaki

From page 10399: The following three changes should be made. Change “In 2018, the catalytic cross coupling reaction of arenes and aryl iodides via metal–ligand cooperative sp2 C–H bond cleavage was reported by Albéniz and co-workers.75“ To “In 2014, Houk, Yu, and Wu clarified experimentally and computationally that amino acid ligand-assisted Pd-catalyzed sp2 C–H alkenylation involved metal–ligand cooperative C–H bond cleavage. (1) Furthermore, Yu and his co-workers expanded the mechanism to pyridone-hydroxypyridine cooperation, demonstrating numerous number of catalytic C–H bond functionalizations. (2) In 2018, Albéniz and co-workers further supported the cooperative effect of the pyridone/hydroxypyridine palladium complexes in C–H bond arylation.75” Delete “Further experimental analysis, such as isolation of intermediates, kinetic analyses, would lead to improvement of the activities and development of other unique catalytic reactions.” Change “Until quite recently, almost no metal–ligand cooperative concerted cleavage or formation has been reported” To “Until quite recently, almost no metal–ligand cooperative concerted cleavage or formation has been reported as an elementary reaction.” We are grateful to Jin-Quan Yu for pointing out our oversight. This article references 2 other publications. For representative papers, see: This article has not yet been cited by other publications.

中文翻译:


通过金属-配体合作对 Si-H、B-H 和 C-H 键裂解的添加和校正



从第 10399 页开始:应进行以下三项更改。更改 “2018 年,Albéniz 及其同事报道了芳烃和芳基碘化物通过金属-配体合作 sp2 C-H 键裂解的催化交叉偶联反应。75“ 到 ”2014 年,Houk、Yu 和 Wu 通过实验和计算阐明了氨基酸配体辅助 Pd 催化的 sp2 C-H 烯基化涉及金属-配体协同 C-H 键裂解。(1) 此外,Yu 和他的同事将机制扩展到吡啶酮-羟基吡啶合作,展示了大量的催化 C-H 键功能化。(2) 2018 年,Albéniz 及其同事进一步支持吡啶酮/羟基吡啶钯配合物在 C-H 键芳基化中的协同作用。75“ 删除 ”进一步的实验分析,例如中间体的分离、动力学分析,将导致活性的改进和其他独特催化反应的开发。”将“直到最近,几乎没有金属-配体协同协同切割或形成的报道”改为“直到最近,几乎没有金属-配体协同协同切割或形成作为基本反应的报道。我们感谢 Jin-Quan Yu 指出我们的疏忽。本文引用了其他 2 篇出版物。代表性论文见:本文尚未被其他出版物引用。
更新日期:2024-10-31
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