In the past few years, researchers have emphasized the development of metal-organic frameworks (MOFs), which are made up of metallic ions and organic compounds as ligands. MOFs have an extensive list of potential applications as corrosion-inhibiting nanomaterials due to inherent notable characteristics, which include an enormous effective area, pore size manipulation, changeable behavior and molecular framework, and a wide range of potentially active domains. The current review focuses on the latest research on the utilization of metal-organic frameworks as anti-corrosive material. Herein, this review focuses on the latest research progress of MOF-based corrosion protection materials and reviews their anticorrosion performance, including the commonly concerned synthesis approaches of MOFs for corrosion protection with their respective advantages and shortcomings, the different anticorrosion applications, latest techniques used for screening MOF corrosion inhibition performance and the presented challenges that need to be conquered in practical applications. Meanwhile, we explained the corrosion protection mechanisms of MOFs when serve as inhibitors, nano-containers, and surface protecting coatings. At the end of this review, the future outlooks of MOFs for corrosion protection is provided, we hope this review will illuminate the achievement of high performed anticorrosion MOFs and offer new ideas for the development of MOF-based materials for future corrosion protection application.

中文翻译：

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金属有机框架 （MOFs） 作为多功能材料的研究进展：设计、合成和防腐性能技术


在过去的几年里，研究人员强调了金属有机框架 （MOF） 的发展，它由金属离子和有机化合物作为配体组成。由于固有的显着特性，MOF 作为腐蚀抑制纳米材料具有广泛的潜在应用，包括巨大的有效面积、孔径操纵、可变的行为和分子框架，以及广泛的潜在活性域。目前的综述侧重于关于利用金属有机框架作为防腐材料的最新研究。本文重点介绍了MOF基防腐材料的最新研究进展，综述了其防腐性能，包括人们普遍关注的MOFs防腐合成方法及其各自的优缺点、不同的防腐应用、筛选MOF防腐性能的最新技术以及实际应用中需要克服的挑战。同时，我们解释了 MOF 用作抑制剂、纳米容器和表面保护涂层时的腐蚀保护机制。在这篇综述的最后，提供了 MOF 用于腐蚀保护的未来展望，我们希望这篇综述能够阐明高性能防腐 MOF 的成就，并为未来腐蚀保护应用的 MOF 基材料的开发提供新思路。