Ordered intermetallics contribute to a unique class of catalyst materials due to their rich atomic features. Further engineering of ordered intermetallics at a mesoscopic scale is of great importance to expose more active sites and introduce new functions. Recently, multidimensionally ordered mesoporous intermetallic (MOMI) nanoarchitectonics, which subtly integrate atomically ordered intermetallics and mesoscopically ordered mesoporous structures, have held add-in synergies that not only enhance catalytic activity and stability but also optimize catalytic selectivity. In this tutorial review, we have summarized the latest progress in the rational design, targeted synthesis, and catalytic applications of MOMIs, with a special focus on the findings of our group. Three strategies, including concurrent template route, self-template route, and dealloying route, are discussed in detail. Furthermore, physicochemical properties and catalytic performances for several important reactions are also described to highlight the remarkable activity, high stability, and controllable selectivity of MOMI nanoarchitectonics. Finally, we conclude with a summary and explore future perspectives in the field to contribute to wider applications.

中文翻译：

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多维有序介孔金属间化合物：用于高级催化的前沿纳米结构学


有序金属间化合物由于其丰富的原子特性而有助于成为一类独特的催化剂材料。在细观尺度上进一步设计有序金属间化合物对于揭示更多活跃位点并引入新功能非常重要。最近，多维有序介孔金属间化合物 （MOMI） 纳米结构巧妙地整合了原子有序的金属间化合物和介观有序的介孔结构，具有附加的协同作用，不仅可以增强催化活性和稳定性，还可以优化催化选择性。在本教程综述中，我们总结了 MOMIs 的合理设计、靶向合成和催化应用的最新进展，特别关注了我们小组的研究结果。详细讨论了三种策略，包括并发模板路线、自模板路线和脱合金路线。此外，还描述了几个重要反应的物理化学性质和催化性能，以突出 MOMI 纳米结构学的显着活性、高稳定性和可控选择性。最后，我们总结并探索该领域的未来前景，以促进更广泛的应用。