当前位置: X-MOL 学术Adv. Synth. Catal. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Front Cover Picture: Dearomative 1,2‐(Deutero)Hydrotrifluoromethylation of Chromium‐Bound Arenes (Adv. Synth. Catal. 20/2024)
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2024-10-26 , DOI: 10.1002/adsc.202401219
Cheng‐Jie Wu, Xu Jiang, Jia‐Yi Qiu, Ming‐Yang Wang, Wei Li

The front cover presents the conversion of simple benzene derivatives into high-value trifluoromethyl-containing cyclohexadienes. The background shows the gate of Qiushi Academy, which is the former site of Zhejiang University. With a chromium-mediated η6-coordination strategy to activate inert arene π-bonds, both dearomative 1,2-hydrotrifluoromethylation and dearomative 1,2-deuterotrifluoromethylation were readily realized. More details can be found in the Communication by Wei Li and co-workers (C.-J. Wu, X. Jiang, J.-Y. Qiu, M.-Y. Wang, W. Li, Adv. Synth. Catal. 2024, 366, 4195–4199; DOI: 10.1002/adsc.202400718)

中文翻译:


封面图片:铬结合芳烃的去铝 1,2-(氘代)氢三氟甲基化 (Adv. Synth.加泰罗尼亚。20/2024)



封面展示了简单苯衍生物转化为高价值含三氟甲基的环己二烯。背景是求是书院的大门,这里是浙江大学的旧址。通过铬介导的 η6-配位策略激活惰性芳烃 π-键,去氨基 1,2-氢三氟甲基化和去氨基 1,2-氘三氟甲基化都很容易实现。更多详细信息可以在 Wei Li 及其同事 (C.-J.吴晓晓 江 J.-Y.邱 M.-Y.Wang, W. Li, Adv. Synth.加泰罗尼亚2024366, 4195–4199;DOI: 10.1002/adsc.202400718)
更新日期:2024-10-26
down
wechat
bug