Mn(OAc)₃ has emerged as a highly valuable one-electron oxidant in the fields of synthetic and medicinal chemistry, owing to its mild reactivity, economic feasibility, and low toxicity. In recent years, significant advancements have been made in Mn(OAc)₃ chemistry, markedly expanding the boundaries of synthetic radical chemistry. This review offers a consolidated and critical overview of the latest developments and applications of Mn(OAc)₃ in organic synthesis over the past decade. The emphasis is placed on efforts that strive to achieve milder reaction conditions and broaden the range of synthesis opportunities. It is our intention that this review will serve as a valuable reference for the synthetic and medicinal chemistry communities, inspiring further exploration and innovation in this dynamic field.

中文翻译：

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有机合成中的乙酸锰 （III）：过去十年回顾


Mn（OAc）₃ 由于其温和的反应性、经济可行性和低毒性，已成为合成和药物化学领域中一种非常有价值的单电子氧化剂。近年来，Mn（OAc）₃ 化学取得了重大进展，显著拓展了合成自由基化学的边界。本文对过去十年中 Mn（OAc）₃ 在有机合成中的最新发展和应用进行了综合和批判性的概述。重点放在努力实现更温和的反应条件和扩大合成机会范围的努力上。我们的目的是让这篇综述成为合成和药物化学界的宝贵参考，激发在这个充满活力的领域的进一步探索和创新。