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Synergistic effects in organic mixtures for enhanced catalytic hydrogenation and hydrodeoxygenation
Chem Catalysis ( IF 11.5 ) Pub Date : 2024-10-16 , DOI: 10.1016/j.checat.2024.101135 Ankit Mathanker, Sahil Halarnkar, Bolton Tran, Nirala Singh, Bryan R. Goldsmith
Chem Catalysis ( IF 11.5 ) Pub Date : 2024-10-16 , DOI: 10.1016/j.checat.2024.101135 Ankit Mathanker, Sahil Halarnkar, Bolton Tran, Nirala Singh, Bryan R. Goldsmith
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The hydrogenation and hydrodeoxygenation (HDO) of organic mixtures are important processes in bio-oil conversion and plastics upcycling. Understanding how the presence of co-reactants in organic mixtures affects the kinetics is critical for designing reactors that can convert these mixtures into desired products. Here, we discuss cases in (electro)catalysis where the presence of a co-reactant R 2 enhances the rate of hydrogenation or HDO of another reactant R 1 beyond the rate if only R 1 is present. We divide the discussion into simple and complex mutual influences. Simple mutual influences occur when the presence of R 2 does not change the mechanism or values of rate constants of elementary steps for R 1 . A complex mutual influence of R 2 on R 1 occurs if the presence of R 2 changes the rate constants of elementary steps involving R 1 . We discuss challenges and opportunities in discerning the different mutual influences and increasing their synergistic effects in organic mixtures.
更新日期：2024-10-16
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