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Grease trap waste valorization through hydrothermal liquefaction and anaerobic digestion: a circular approach to dairy wastewater treatment
Energy & Environmental Science ( IF 32.4 ) Pub Date : 2024-10-16 , DOI: 10.1039/d4ee02245a
Daniela V. Cabrera, Ingrid Adema-Yusta, María J. Santibañez, Crispin Celis, Jefferson W. Tester, Rodrigo A. Labatut

Grease traps are commonly used in the dairy industry to separate fats from their generated wastewater. Due to its properties, grease trap waste (GTW) is predominantly incinerated or landfilled despite its high energy content. In this study, hydrothermal liquefaction (HTL) was used to convert dairy industry GTW into biocrude while the generated HTL-wastewater (AP) was subjected to anaerobic digestion (AD) to recover biomethane. To maximize organic carbon to biocrude conversion, and to minimize the use of freshwater, a fraction of the AP was recirculated in subsequent HTL reactions. AP recirculation increased biocrude yields (73 vs. 78 wt%) but decreased both the higher heating value (HHV) (38 vs. 37 MJ kg−1) and the fraction (72 vs. 64%) of lighter hydrocarbons. Continuous AD using an EGSB reactor proved to be an effective method to further reduce the COD of the AP from 6.5 g L−1 to 0.7 g L−1 and enhance the overall energy recovery of the GTW from 81% (HTL only) to 83.1% (HTL-AD). Integrating HTL with AD and recycling a fraction of the AP in the HTL process allows for efficient wastewater treatment and a recovery of up to 84.8% of the energy contained in the GTW.

中文翻译:


通过水热液化和厌氧消化实现隔油池废物价值化:乳品废水处理的循环方法



隔油池通常用于乳制品行业,以从产生的废水中分离脂肪。由于其特性,尽管隔油池废物 (GTW) 的能量含量很高,但主要被焚烧或填埋。在本研究中,使用水热液化 (HTL) 将乳制品工业 GTW 转化为生物原油,同时对生成的 HTL 废水 (AP) 进行厌氧消化 (AD) 以回收生物甲烷。为了最大限度地提高有机碳到生物原油的转化率,并最大限度地减少淡水的使用,在随后的 HTL 反应中,一部分 AP 被再循环。AP 再循环提高了生物原油产量(73 vs. 78 wt%),但降低了较轻烃的高热值 (HHV)(38 vs. 37 MJ kg-1)和馏分(72 vs. 64%)。使用 EGSB 反应器的连续 AD 被证明是一种有效的方法,可将 AP 的 COD 从 6.5 g L-1 降低到 0.7 g L-1,并将 GTW 的整体能量回收率从 81%(仅 HTL)提高到 83.1%(HTL-AD)。将 HTL 与 AD 集成并在 HTL 工艺中回收一小部分 AP,可以实现高效的废水处理,并回收高达 84.8% 的 GTW 中包含的能量。
更新日期:2024-10-16
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