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Simple physical organic model to predict mechanochemical bond-breaking
Chem ( IF 19.1 ) Pub Date : 2024-10-10 , DOI: 10.1016/j.chempr.2024.09.010
Manabu Abe

Mechanochemical force can pull apart specific bonds, an action that is crucial for efficient and selective chemical transformations. Predicting chemical reactivity under tension force unlocks the selective bond cleavage reaction using ultrasonic irradiation. In this issue of Chem, Craig, Kulik, Moore, and colleagues developed an intuitive physical organic model to understand and predict the chemical reactivity of carbon-carbon bonds under tension.

中文翻译:


用于预测机械化学键断裂的简单物理有机模型



机械化学力可以拉开特定的键,这一作用对于高效和选择性的化学转化至关重要。预测张力下的化学反应性使用超声照射解锁选择性键裂解反应。在本期 Chem 中,Craig、Kulik、Moore 及其同事开发了一个直观的物理有机模型,用于理解和预测碳-碳键在张力下的化学反应性。
更新日期:2024-10-10
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