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A Zeolite-Templated Carbon Synthesized from Extralarge-Pore Zeolite ZEO-1
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2024-10-04 , DOI: 10.1021/acs.inorgchem.4c02984
Lindiane Bieseki, Aurélien Habrioux, Jean-Louis Paillaud, Sibele Pergher, Julie Rousseau, Isabelle Batonneau-Gener, Emmanuel Oheix, Alexander Sachse

A new member of the zeolite-templated carbon (ZTC) family with unprecedented properties has been developed using extralarge-pore zeolite ZEO-1 (JZO) as a template. The resulting ZTC-JZO exhibits strong X-ray diffraction long-range order, replicating three distinct zeolite planes with different lattice spacings. By harnessing the enhanced micropore void volume in the ZEO-1 template, we achieved the first ZTC with a bimodal micropore size distribution, resulting in superior skeleton density and thickness. The ZTC-JZO presents high electrical conductivity and demonstrates improved electrocatalytic activity in the oxygen reduction reaction.

中文翻译:


由超大孔沸石 ZEO-1 合成的沸石模板碳



使用超大孔沸石 ZEO-1 (JZO) 作为模板开发了沸石模板碳 (ZTC) 家族的新成员,具有前所未有的性能。所得的 ZTC-JZO 表现出很强的 X 射线衍射长程有序性,复制了具有不同晶格间距的三个不同的沸石平面。通过利用 ZEO-1 模板中增强的微孔空隙体积,我们实现了第一个具有双峰微孔尺寸分布的 ZTC,从而获得了卓越的骨架密度和厚度。ZTC-JZO 具有高导电性,并在氧还原反应中表现出改进的电催化活性。
更新日期:2024-10-09
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