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Organometallic Iridium-Complex-Functionalized Nanographene Catalysts for Low-Temperature Hydrogenation of Carbonyl Derivatives
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2024-10-03 , DOI: 10.1021/acs.inorgchem.4c03602
Li-Jun Zhao, Shixin Zhang, Qing Zhou, Hangyu Zhou, Yue Zhao, Ke Yang, Huijuan Su, Libo Sun, Xun Sun, Peng Xiao, Caixia Qi

An organometallic iridium (Ir)-complex-functionalized nanographene catalyst Ir-PyPh-GC was prepared via a two-step strategy involving amide ligand modification and metal Ir coordination. Ir-PyPh-GC showed ultrahigh hydrogenation capability, good recyclability, and selectivity for carbonyl derivatives (ketones, aldehydes, and quinones) at a low temperature (40 °C). The as-prepared Ir-complex-based catalyst is less expensive, making it feasible for industrial application.

中文翻译:


用于羰基衍生物低温加氢的有机金属铱络合功能化纳米石墨烯催化剂



通过酰胺配体修饰和金属 Ir 配位两步策略制备了有机金属铱 (Ir) 配合功能化纳米石墨烯催化剂 Ir-PyPh-GCIr-PyPh-GC 在低温 (40 °C) 下表现出超高的氢化能力、良好的可回收性和对羰基衍生物(酮、醛和醌)的选择性。所制备的基于 Ir 络合物的催化剂成本较低,使其可用于工业应用。
更新日期:2024-10-03
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