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A “bricks-and-mortar” structured graphene oxide/polyvinyl alcohol coating: enhanced water interfacial lubrication and durability
Friction ( IF 6.3 ) Pub Date : 2024-09-27 , DOI: 10.1007/s40544-024-0902-7
Hanglin Li, Lin Ding, Jingchun Zhang, Zhaoyang Guo, Yazhuo Shang, Honglai Liu, Xiangqiong Zeng, Jiusheng Li

Coatings serve as ideal protective films for mechanical systems, providing dependable as well as efficient lubrication because of their unique structure along with outstanding tribological characteristics. Inspired by the “bricks-and-mortar” structure, we prepared layered graphene oxide (GO) composite finishes strengthened with polyvinyl alcohol (PVA) and borax. Our study demonstrates that the tribological properties of the GO-based coating on 304 stainless steel (SS304) are potentially greatly affected through PVA, GO, and annealing. By optimizing the composition, we achieved the PVA40 wt%/GO0.01 wt%/borax composite coating, which exhibited the lowest average coefficient of friction (COF) of 0.021±0.003 (a 97.86% reduction compared to control SS304) with minimal wear and abrasion even in a water environment. We found that the enhanced mechanical characteristics as well as elastic recovery within the coating were attributed to the hydrogen bonds and cross-linking between PVA and borax, which led to stress distribution. Reduced friction was further aided by the formation of a hydrated layer at the friction interface. As a result, the coating demonstrated remarkable durability, maintaining a low COF during long sliding distances (576 m, 28,800 cycles, significantly longer than previously reported) without breaking.



中文翻译:


“砖块和砂浆”结构的氧化石墨烯/聚乙烯醇涂层:增强水界面润滑和耐用性



涂层作为机械系统的理想保护膜,由于其独特的结构和出色的摩擦学特性,提供可靠且高效的润滑。受“砖块和砂浆”结构的启发,我们制备了用聚乙烯醇(PVA)和硼砂增强的层状氧化石墨烯(GO)复合饰面。我们的研究表明,PVA、GO 和退火可能会对 304 不锈钢 (SS304) 上的 GO 涂层的摩擦学性能产生很大影响。通过优化成分,我们获得了 PVA 40 wt% /GO 0.01 wt% /硼砂复合涂层,其平均摩擦系数 (COF) 最低,为 0.021±0.003(与对照 SS304 相比减少了 97.86%),并且磨损最小即使在水环境中也能防止磨损。我们发现,涂层内增强的机械特性和弹性恢复归因于 PVA 和硼砂之间的氢键和交联,从而导致应力分布。在摩擦界面处形成水合层进一步有助于减少摩擦。因此,该涂层表现出卓越的耐用性,在长滑动距离(576 m,28,800 次循环,明显长于之前报道的时间)内保持较低的摩擦系数而不会破裂。

更新日期:2024-09-27
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