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Integrated photochemical strategy for alkene synthesis from diverse substrates
Nature Chemistry ( IF 19.2 ) Pub Date : 2024-09-27 , DOI: 10.1038/s41557-024-01643-5


Despite advances, a general olefination strategy for the direct conversion of carboxylic acids, alcohols and alkanes into alkenes remains challenging owing to their inherent differences in reactivity. Now, a one-pot photochemical method comprising a Giese addition followed by a Norrish type-II fragmentation enables the on-demand production of alkenes from diverse substrates.

中文翻译:


从不同底物合成烯烃的集成光化学策略



尽管取得了进展,但由于羧酸、醇和烷烃的固有反应性差异,将羧酸、醇和烷烃直接转化为烯烃的一般烯化策略仍然具有挑战性。现在,一种包括 Giese 添加和 Norrish II 型碎裂的一锅法光化学方法能够从不同的基材按需生产烯烃。
更新日期:2024-09-27
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