Organoboron chemistry has become a cornerstone of modern synthetic methodology. Most of these reactions use an organoboron starting material that contains just one C(sp²)–B or C(sp³)–B bond; however, there has been a recent and accelerating trend to prepare multiborylated alkanes that possess two or more C(sp³)–B bonds. This is despite a lack of general reactivity, meaning many of these compounds currently offer limited downstream synthetic value. This Review summarizes recent advances in the exploration of multiborylated alkanes, including a discussion on how these products may be elaborated in further synthetic manipulations.

中文翻译：

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多重硼酸化烷烃的当前用途和未来潜力

有机硼化学已成为现代合成方法的基石。这些反应中的大多数使用仅包含一个 C（sp²）–B 或 C（sp³）–B 键的有机硼起始材料;然而，最近出现了一种加速的趋势，即制备具有两个或多个 C（sp³）-B 键的多重硼酸化烷烃。尽管缺乏一般反应性，这意味着这些化合物中的许多化合物目前提供的下游合成价值有限。本综述总结了勘探多重硼酸化烷烃的最新进展，包括关于如何在进一步的合成操作中详细阐述这些产品的讨论。