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Phenacyl esters of acetic acid derivatives and their application for the synthesis of 2-oxo-4-phenyl-5-(phenylhydrazono)-2,5-dihydro-furan-3-derivatives
Journal of Heterocyclic Chemistry ( IF 2.0 ) Pub Date : September 2008 , DOI: 10.1002/jhet.5570450529
Jan Hlaváč , Pavel Hradil , Radek Mělnický , Lubomír Kvapil , Petr Šlézar , Martin Grepl-- , Pavel Hradil , Antonín Lyčka , Martin Grepl

Coupling of various substituted phenacyl acetates 1 and diazonium salts 3 was studied. If the phenacyl acetates were substituted by an electronaceptor group such as CN or COOEt 3-substituted phenyl-5-(phenyl-hydrazono)-5H-furan-2-ones 4 were formed. Also synthesis of aza and diaza analogs is described. The compounds were characterized using MS and NMR spectroscopy.

中文翻译:

乙酸衍生物的苯甲酸酯及其在2-氧代-4-苯基-5-(苯基肼基)-2,5-二氢呋喃-3-衍生物的合成中的应用

研究了各种取代的乙酸苯甲酰乙酸酯1和重氮盐3的偶联。如果苯甲酰甲基乙酸盐是由一个electronaceptor基团如CN或COOEt烷基取代的3-取代的苯基-5-(苯基-亚肼基)-5- ħ -呋喃-2-酮4形成。还描述了氮杂和二氮杂类似物的合成。使用MS和NMR光谱对化合物进行表征。
更新日期:2017-01-31
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