A straightforward and stepwise functionalization of poly(limonene carbonate) (PLC) was achieved through the use of thiol–ene click chemistry introducing primary amine groups. These amines are initiating points for N-carboxy anhydride (NCA) ring-opening polymerization (ROP) reactions, allowing us to modify the PLC backbone with oligolysine fragments, thereby creating a polymer brush type macromolecule. These newly prepared biohybrid structures show a clear hydrophilic behavior as evident from their physical behavior and contact angle measurements.

中文翻译：

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生物衍生的聚（柠檬烯碳酸酯）-寡赖氨酸杂化大分子的受控合成


通过使用引入伯胺基团的巯基-烯点击化学，实现了聚碳酸柠檬烯 （PLC） 的直接和逐步官能化。这些胺是 N-羧基酸酐 （NCA） 开环聚合 （ROP） 反应的起始点，使我们能够用寡赖氨酸片段修饰 PLC 骨架，从而产生聚合物刷状大分子。这些新制备的生物杂化结构显示出明显的亲水行为，从它们的物理行为和接触角测量中可以明显看出。