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Control of the electron spin state for enhancing plasmonic nitrogen fixation
Chem Catalysis ( IF 11.5 ) Pub Date : 2024-09-19 , DOI: 10.1016/j.checat.2024.101112 Penglei Wang , Boyuan Wu , Hao Wu , Jianfang Wang
中文翻译:
控制电子自旋状态以增强等离子体固氮
更新日期:2024-09-19
Chem Catalysis ( IF 11.5 ) Pub Date : 2024-09-19 , DOI: 10.1016/j.checat.2024.101112 Penglei Wang , Boyuan Wu , Hao Wu , Jianfang Wang
In this issue of Chem Catalysis, Wang et al. have synthesized a single-atom Au3Fe1/Mo alloy featuring medium-spin Fe(III) through an alloying strategy to enhance plasmonic nitrogen fixation. The enhancement mechanism has been found to originate from the medium-spin Fe centers acting as active sites that facilitate the adsorption and activation of nitrogen molecules.
中文翻译:
控制电子自旋状态以增强等离子体固氮
在本期《化学催化》中,王等人。通过增强等离子体固氮的合金化策略,合成了具有中等自旋 Fe(III) 的单原子 Au 3 Fe 1 /Mo 合金。研究发现,这种增强机制源于中自旋铁中心作为活性位点,促进氮分子的吸附和活化。