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Control of Dynamic Chirality in Donor-Acceptor Fluorophores
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-09-17 , DOI: 10.1002/anie.202414490
Max Coehlo 1 , Lucas Frédéric 2 , Laurélie Poulard 1 , Nawal Ferdi 3 , Lilian Estaque 4 , Alaric Desmarchelier 1 , Gilles Clavier 2 , Jean-Pierre Dognon 5 , Ludovic Favereau 6 , Michel Giorgi 7 , Jean-Valère Naubron 8 , Grégory Pieters 9
Affiliation  

We present a molecular design where the dynamic chirality of donor-acceptor fluorophores is controlled using a configurationally stable chiral unit. Beyond illustrating the potential of dynamic chirality control to facilitate the access to chiral functional materials, this work highlight the positive influence of chiral perturbation from the configurationally stable chiral unit on the dissymmetry factors of the dynamically chiral fluorophores.

中文翻译:


供体-受体荧光团中动态手性的控制



我们提出了一种分子设计,其中供体 - 受体荧光团的动态手性使用构型稳定的手性单元进行控制。除了说明动态手性控制促进获得手性功能材料的潜力外,这项工作还强调了来自构型稳定的手性单元的手性扰动对动态手性荧光团不对称因子的积极影响。
更新日期:2024-09-17
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