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Triple Regulations via Fe Redox Boosting Nitrate Reduction to Ammonia at Industrial Current Densities
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-09-16 , DOI: 10.1002/anie.202415300
Wenhao Yang, Ziwei Chang, Xu Yu, Ruxiang Shen, Lianzhou Wang, Xiangzhi Cui, Jianlin Shi

The performance of low-valence Fe doped Ni2P toward NO3RR to NH3 is significantly enhanced via the three regulations of Fe through bypassing the rate-determining NO3 to NO2 step, reducing the NO2 to NH3 reaction energy barrier, and prohibiting the competitive hydrogen evolution.

中文翻译:


通过 Fe 氧化还原实现三重调节,在工业电流密度下促进硝酸盐还原为氨



通过绕过速率确定 NO3 到 NO2 的步骤,降低 NO2 到 NH3 的反应能垒,并禁止竞争性析氢,通过 Fe 的三个调节显着提高了低价 Fe 掺杂 Ni2P 对 NO3RR 到 NH3 的性能。
更新日期:2024-09-16
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