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Triple Regulations via Fe Redox Boosting Nitrate Reduction to Ammonia at Industrial Current Densities
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-09-16 , DOI: 10.1002/anie.202415300 Wenhao Yang, Ziwei Chang, Xu Yu, Ruxiang Shen, Lianzhou Wang, Xiangzhi Cui, Jianlin Shi
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-09-16 , DOI: 10.1002/anie.202415300 Wenhao Yang, Ziwei Chang, Xu Yu, Ruxiang Shen, Lianzhou Wang, Xiangzhi Cui, Jianlin Shi
The performance of low-valence Fe doped Ni2P toward NO3−RR to NH3 is significantly enhanced via the three regulations of Fe through bypassing the rate-determining NO3− to NO2− step, reducing the NO2− to NH3 reaction energy barrier, and prohibiting the competitive hydrogen evolution.
中文翻译:
通过 Fe 氧化还原实现三重调节,在工业电流密度下促进硝酸盐还原为氨
通过绕过速率确定 NO3− 到 NO2− 的步骤,降低 NO2− 到 NH3 的反应能垒,并禁止竞争性析氢,通过 Fe 的三个调节显着提高了低价 Fe 掺杂 Ni2P 对 NO3−RR 到 NH3 的性能。
更新日期:2024-09-16
中文翻译:
通过 Fe 氧化还原实现三重调节,在工业电流密度下促进硝酸盐还原为氨
通过绕过速率确定 NO3− 到 NO2− 的步骤,降低 NO2− 到 NH3 的反应能垒,并禁止竞争性析氢,通过 Fe 的三个调节显着提高了低价 Fe 掺杂 Ni2P 对 NO3−RR 到 NH3 的性能。