MnNCN nanoparticles were first discovered to be robust for the ammoxidation of alcohols into nitriles, while the extensively studied MnO_x produced amides under identical conditions. Besides the high activity and selectivity, MnNCN demonstrated wide substrate scope including primary alcohols, secondary alcohols, phenyl substituted aliphatic alcohols, as well as diols.

中文翻译：

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碳二亚胺锰 （MnNCN）：一种用于从醇中选择性合成腈的新型非均相 Mn 催化剂


MnNCN 纳米颗粒最初被发现对醇氧化成腈具有稳健性，而广泛研究的 MnO_x 在相同条件下产生酰胺。除了高活性和选择性外，MnNCN 还表现出广泛的底物范围，包括伯醇、仲醇、苯取代脂肪醇以及二醇。