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Ni(0)-Catalyzed Rearrangement of Vinylcyclobutanones (VCBOs) to Synthesize Six-Membered Non-Conjugated Enones
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-09-15 , DOI: 10.1002/anie.202417407 Jiguo Ma, Jicheng Duan, Zhi-Xiang Yu
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-09-15 , DOI: 10.1002/anie.202417407 Jiguo Ma, Jicheng Duan, Zhi-Xiang Yu
A Ni-catalyzed rearrangement of vinylcyclobutanones via vinyl-group assisted C−C cleavage enables the synthesis of non-conjugated six-membered enones, which are important and difficult to be accessed through other methods.
中文翻译:
Ni(0) 催化的乙烯基环丁酮 (VCBO) 重排合成六元非共轭烯酮
通过乙烯基辅助 C-C 裂解的乙烯基环丁酮的 Ni 催化重排能够合成非共轭六元烯酮,这很重要且难以通过其他方法获得。
更新日期:2024-09-15
中文翻译:
Ni(0) 催化的乙烯基环丁酮 (VCBO) 重排合成六元非共轭烯酮
通过乙烯基辅助 C-C 裂解的乙烯基环丁酮的 Ni 催化重排能够合成非共轭六元烯酮,这很重要且难以通过其他方法获得。