Development and Application of O-(Trimethylsilyl)aryl Fluorosulfates for the Synthesis of Arynes,The Journal of Organic Chemistry

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Development and Application of O-(Trimethylsilyl)aryl Fluorosulfates for the Synthesis of Arynes
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2015-06-17 00:00:00 , DOI: 10.1021/acs.joc.5b00923
Qiao Chen ₁ , Hongmei Yu ₁ , Zhaoqing Xu ₁ , Li Lin ₁ , Xianxing Jiang ₂ , Rui Wang ₁

Affiliation

A class of o-(trimethylsilyl)aryl fluorosulfates was synthesized by a concise method and successfully used as aryne precursors for the first time. Different trapping agents such as azides, furans, and acyl acetoacetates could successfully react with the aryne precursors under mild conditions with good to excellent yields.

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