Loading Lewis Acid/Base Pair on Metal Nanocluster for Catalytic Ugi Reaction,Angewandte Chemie International Edition

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Loading Lewis Acid/Base Pair on Metal Nanocluster for Catalytic Ugi Reaction
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-09-13 , DOI: 10.1002/anie.202413861
Ji-Qiang Fan ₁ , Yanshuang Li ₂ , Wen Wu Xu ₂ , Man-Bo Li ₃

Affiliation

A metal nanocluster Au₃₅Cd₂(PNP)(SAdm)₁₈Cl with both Lewis acid and Lewis base sites has been synthesized and characterized. It was developed as an efficient catalyst for the Ugi reaction, exhibiting high TOF, mild conditions, broad substrate scope and exceptional catalyst recyclability. Synergistic effect of the Lewis acid/Lewis base pair on the metal nanocluster has been verified as contributing to its high catalytic activity.

中文翻译：

在金属纳米簇上加载路易斯酸/碱对用于催化 Ugi 反应

已经合成并表征了具有路易斯酸和路易斯碱位点的金属纳米团簇 Au₃₅Cd₂（PNP）（SAdm）₁₈Cl。它是作为 Ugi 反应的高效催化剂开发的，具有高 TOF、温和的条件、广泛的底物范围和出色的催化剂可回收性。Lewis acid/Lewis 碱对对金属纳米团簇的协同作用已被证明有助于其高催化活性。

更新日期：2024-09-13

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