Photocatalyzed Aryl C-H Fluorocarbonylation with CF2Br2,Angewandte Chemie International Edition

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Photocatalyzed Aryl C-H Fluorocarbonylation with CF2Br2
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-09-13 , DOI: 10.1002/anie.202414933
Kehan Zhou ₁ , Yuheng Xiao ₁ , Zhibin Huang ₁ , Yingsheng Zhao ₂

Affiliation

Dibromo difluoromethane (CF₂Br₂) is an abundant and inexpensive fluorine source that has rarely been used for C−H fluoroalkylation. This study reveals photocatalyzed, solvent tunable strategy for synthesizing fluorocarbonylated products and difluorobromomethylated products using CF₂Br₂. The diverse transformations of fluorocarbonylated products highlight the utility of this protocol.

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