Kinetic Studies of CO2 Insertion into Metal–Element σ-Bonds,Accounts of Chemical Research

当前位置： X-MOL 学术 › Acc. Chem. Res. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Kinetic Studies of CO2 Insertion into Metal–Element σ-Bonds
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2024-09-13 , DOI: 10.1021/acs.accounts.4c00440
Nilay Hazari ₁

Affiliation

Despite the plethora of metal catalyzed reactions for CO₂ utilization that have been developed in academic laboratories, practical systems remain elusive. The understanding of the elementary steps in catalysis is a proven method to improve catalytic performance. In many catalytic cycles for CO₂ utilization, the insertion of CO₂ into a metal–element σ-bond, such as hydrides, alkyls, amides, or hydroxides, is a crucial step. However, despite the many demonstrations of CO₂ insertion, there are a paucity of kinetic studies, and information about the reaction mechanism has been predominantly elucidated from computational investigations. In this Account, kinetic studies on CO₂ insertion into late transition metal–element σ-bonds performed by my group are summarized, along with their implications for catalysis.

中文翻译：

CO2 插入金属元素 σ 键的动力学研究

尽管学术实验室已经开发了大量用于 CO₂ 利用的金属催化反应，但实际系统仍然难以捉摸。了解催化的基本步骤是提高催化性能的行之有效的方法。在许多 CO₂ 利用的催化循环中，将 CO₂ 插入金属元素σ键（如氢化物、烷基、酰胺或氢氧化物）中是一个关键步骤。然而，尽管有许多 CO₂ 插入的证明，但缺乏动力学研究，有关反应机制的信息主要通过计算研究来阐明。在本帐户中，总结了我的小组进行的 CO₂ 插入晚期过渡金属元素 σ 键的动力学研究，以及它们对催化的影响。

更新日期：2024-09-13

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南