Photoredox-Catalyzed Difunctionalization of Alkenes with Sulfilimines,Organic Letters

当前位置： X-MOL 学术 › Org. Lett. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Photoredox-Catalyzed Difunctionalization of Alkenes with Sulfilimines
Organic Letters ( IF 4.9 ) Pub Date : 2024-09-10 , DOI: 10.1021/acs.orglett.4c02971
Tingwei Yu ₁ , Zhe Jin ₁ , Yan Ji ₁ , Aihong Yang ₁ , Penghao Jia ₁

Affiliation

Herein, we disclose a facile photoinduced difunctionalization of alkenes, enabling the synthesis of valuable β-amino alcohols, β-amino ethers, and 1,2-diamines with diverse nucleophiles. The protocol relies on the use of readily accessible dibenzothiophene-based sulfilimines as novel N-radical precursors, showcasing high functional-group tolerance and exclusive regioselectivity under mild reaction conditions.

中文翻译：