Visible Light-Switchable Lattice Oxygen Sites for Selective C−H and C(O)−C Bond Electrooxidation,Angewandte Chemie International Edition

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Visible Light-Switchable Lattice Oxygen Sites for Selective C−H and C(O)−C Bond Electrooxidation
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-09-09 , DOI: 10.1002/anie.202410555
Keping Wang ₁ , Jinshu Huang ₁ , Jinguang Hu ₂ , Mei Wu ₁ , Yuhe Liao ₃ , Song Yang ₁ , Hu Li ₁

Affiliation

A visible light-switching strategy for in situ formulating stationary or removable lattice-oxygen sites in ESE-NiOOH is developed with ultrahigh selectivity for electrocatalytic upgrading of aromatic secondary alcohols via direct dehydrogenation to acetophenones or C(O)−C bond cleavage to benzoic acids. Precisely modulating lattice-oxygen removability is reported for the first time to activate C−H and vector downstream reactions.

中文翻译：

用于选择性 C-H 和 C（O）-C 键电氧化的可见光可切换晶格氧位点

开发了一种可见光开关策略，用于在 ESE-NiOOH 中原位配制固定或可移除的晶格氧位点，具有超高选择性，用于通过直接脱氢为苯乙酮或 C（O）-C 键裂解为苯甲酸来电催化提芳烃仲醇。首次报道了精确调节晶格-氧可去除性以激活 C-H 和载体下游反应。

更新日期：2024-09-09

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