Synthesis of Diaryl Ethers via Hypervalent Iodine-Mediated C–H Functionalization,Organic Letters

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Synthesis of Diaryl Ethers via Hypervalent Iodine-Mediated C–H Functionalization
Organic Letters ( IF 4.9 ) Pub Date : 2024-09-09 , DOI: 10.1021/acs.orglett.4c02703
Chenghu Hu _{1,

2} , Qi Jia ₂ , Wenjing Bao ₂ , Guangxing Gu ₂ , Ya Li ₁ , Yanchuan Zhao _{2,

3}

Affiliation

A hypervalent iodine-reagent-based C–H functionalization strategy was utilized to synthesize diaryl ethers. This method directly transforms various arenes into their corresponding diaryliodonium salts, followed by a C–O coupling reaction to produce structurally diverse diaryl ethers. The efficacy of this approach in the late-stage structural modifications of complex molecules was demonstrated.

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