Abstract

A brief review and analysis of research on the relationship between the chemical affinity and the kinetic characteristics of chemical reactions are presented. It is noted that there is a lack of experimental data necessary for the development of the theory, including for correlating the affinity of the chemical process with its rate. Some tendencies of variation of the chemical affinity, as well as the kinetic coefficients correlating the reaction path with its affinity, are considered using the experimental data obtained by the authors on a system with ester synthesis as an example. The potential for developing research in this area is shown.

中文翻译：

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反应过程中化学亲和力的变化

 抽象的

对化学亲和力与化学反应动力学特征关系的研究进行了简要回顾和分析。值得注意的是，缺乏理论发展所需的实验数据，包括将化学过程的亲和力与其速率相关联的实验数据。使用作者在酯合成系统上获得的实验数据作为示例，考虑了化学亲和力的一些变化趋势，以及将反应路径与其亲和力相关的动力学系数。显示了该领域发展研究的潜力。