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A Strongly Coupled Metal/Hydroxide Heterostructure Cascades Carbon Dioxide and Nitrate Reduction Reactions toward Efficient Urea Electrosynthesis
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-09-07 , DOI: 10.1002/anie.202410105
Wei Ye 1 , Ye Zhang 1 , Liang Chen 1 , Fangfang Wu 2 , Yuanhui Yao 1 , Wei Wang 1 , Genping Zhu 1 , Gan Jia 1 , Zhongchao Bai 3 , Shi Xue Dou 3 , Peng Gao 1 , Nana Wang 4 , Guoxiu Wang 5
Affiliation  

A strongly coupled metal/hydroxide heterostructure was constructed. The heterostructure provides dual-sites for carbon dioxide reduction and nitrate reduction reactions, and thus facilitate efficient C−N coupling toward urea formation. The obtained Ag−CuNi(OH)2 composite delivers greatly enhanced urea yield rate and Faradaic efficiency compared with individual Ag and CuNi(OH)2.

中文翻译:


强耦合的金属/氢氧化物异质结构将二氧化碳和硝酸盐还原反应级联到高效的尿素电合成中



构建了强耦合的金属/氢氧化物异质结构。异质结构为二氧化碳还原和硝酸盐还原反应提供了双位点,从而促进了 C-N 耦合以形成尿素。与单独的 Ag 和 CuNi(OH)2 相比,获得的 Ag-CuNi(OH)2 复合材料大大提高了尿素产率和法拉第效率。
更新日期:2024-09-07
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