Supramolecular-macrocycle-based functional organic cocrystals,Chemical Society Reviews

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Supramolecular-macrocycle-based functional organic cocrystals
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2024-09-06 , DOI: 10.1039/d4cs00654b
Susu Ren ₁ , Guan-Yu Qiao ₂ , Jia-Rui Wu ₁

Affiliation

Supramolecular macrocycles, renowned for their remarkable capabilities in molecular recognition and complexation, have emerged as pivotal elements driving advancements across various innovative research fields. Cocrystal materials, an important branch within the realm of crystalline organic materials, have garnered considerable attention owing to their simple preparation methods and diverse potential applications, particularly in optics, electronics, chemical sensing and photothermal conversion. In recent years, macrocyclic entitles have been successfully brought into this field, providing an essential and complementary channel to create novel functional materials, especially those with multiple functionalities and smart stimuli-responsiveness. In this Review, we present an overview of the research efforts on functional cocrystals constructed with macrocycles, covering their design principles, preparation strategies, assembly modes, and diverse functions and applications. Finally, the remaining challenges and perspectives are outlined. We anticipate that this review will serve as a valuable and timely reference for researchers interested in supramolecular crystalline materials and beyond, catalyzing the emergence of more original and innovative studies in related fields.

中文翻译：

基于超分子大环的功能有机共晶体

超分子大环以其在分子识别和络合方面的卓越能力而闻名，已成为推动各种创新研究领域进步的关键要素。共晶材料是结晶有机材料领域的一个重要分支，由于其制备方法简单、应用潜力广泛而受到广泛关注，特别是在光学、电子、化学传感和光热转换等领域。近年来，大环材料已成功引入该领域，为创造新型功能性材料提供了重要且互补的渠道，尤其是那些具有多种功能和智能刺激响应性的材料。在这篇综述中，我们概述了用大环构建的功能共晶的研究工作，包括它们的设计原理、制备策略、组装模式以及各种功能和应用。最后，概述了剩余的挑战和前景。我们预计这篇综述将为对超分子晶体材料及其他领域感兴趣的研究人员提供有价值和及时的参考，并促进相关领域更多原创和创新研究的出现。

更新日期：2024-09-06

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