In this perspective, we explore the historical evolution, photochemical processes, and distinct utility of photoiniferter polymerization. We aim to provide a practical guide encompassing the selection of iniferter and monomer, coupled with the optimization of light wavelengths to conduct efficient photoiniferter polymerizations. We delve into the impact of iniferter structure on photophysical properties and the resulting polymerization behavior. Furthermore, we highlight ongoing research efforts employing photoiniferter polymerization, emphasizing its potential applications in cutting-edge areas of research such as 3D printing and the synthesis of ultra-high molecular weight polymers (10 g mol). Through this perspective, we aim to clarify both the fundamental principles and the practical considerations of photoiniferter polymerization, ultimately advancing its utility and paving the way for innovative applications in polymer science.

中文翻译：

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光引发剂聚合：阐明历史、优势和复兴


从这个角度来看，我们探索了光引发转移剂聚合的历史演变、光化学过程和独特用途。我们的目标是提供实用指南，包括引发转移剂和单体的选择，以及光波长的优化，以进行有效的光引发剂聚合。我们深入研究了引发-终止剂结构对光物理性质和由此产生的聚合行为的影响。此外，我们重点介绍了正在进行的采用光引发剂聚合的研究工作，强调其在 3D 打印和超高分子量聚合物（10 g mol）合成等前沿研究领域的潜在应用。通过这个角度，我们的目标是阐明光引发转移剂聚合的基本原理和实际考虑因素，最终提高其实用性并为聚合物科学的创新应用铺平道路。