Heavier tetrylene- and tetrylyne-transition metal chemistry: it's no carbon copy,Chemical Society Reviews

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Heavier tetrylene- and tetrylyne-transition metal chemistry: it's no carbon copy
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2024-09-04 , DOI: 10.1039/d3cs00226h
Terrance J Hadlington ₁

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Since the late 19th century, heavier tetrylene- and tetrylyne-transition metal chemistry has formed an important cornerstone in both main-group and organometallic chemistry alike. Driven by the success of carbene systems, significant efforts have gone towards the thorough understanding of the heavier group 14 derivatives, with examples now known from across the d-block. This now leads towards applications in cooperative bond activation, and moves ultimately towards well-defined catalytic systems. This review aims to summarise this vast field, from initial discoveries of tetrylene and tetrylyne complexes, to the most recent developments in reactivity and catalysis, as a platform to the future of this exciting, blossoming field.

中文翻译：

较重的四甲苯和四炔过渡金属化学：它不是碳复制品

自 19 世纪末以来，较重的四萘嵌苯和四炔过渡金属化学已成为主族化学和有机金属化学的重要基石。在卡宾系统成功的推动下，人们付出了巨大的努力来彻底了解较重的第 14 族衍生物，现在已经从 d 区了解了一些例子。现在这导致了协同键活化的应用，并最终走向明确的催化系统。本综述旨在总结这一广阔的领域，从四甲苯和四炔配合物的最初发现，到反应性和催化的最新发展，作为这个令人兴奋的、蓬勃发展的领域的未来的平台。

更新日期：2024-09-04

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